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Hi Hanna
Yes I hear you!! valerian is a really strong herb! I've had a similar experience with herbs in the same family (crampbark). Its constituents are quite bitter and so if you had too much it might have caused vasoconstriction instead of dilation! But the bruxism itself might have been what caused the headache. You could possibly try valerian in a tincture instead of the tea. As it is a root it should be prepared as a decoction, which is where you boil the herb for around 15mins or so, depending, and then drink.
I used to grind my teeth every night, less so nowadays, and I'm not exactly sure what the reason is for that! But I have magnesium salt baths almost every night and they are a fantasic way to relax before bed, or passionflower, oat straw, or skullcap are also wonderful herbs that relax the nervous system, and the body. And for dream work, definitely look into mugwort.
Good luck! xx
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